Novel spiro-based hole transporting materials for efficient perovskite solar cells.

نویسندگان

  • Ming-Hsien Li
  • Che-Wei Hsu
  • Po-Shen Shen
  • Hsin-Min Cheng
  • Yun Chi
  • Peter Chen
  • Tzung-Fang Guo
چکیده

Three spiro-acridine-fluorene based hole transporting materials (HTMs), namely CW3, CW4 and CW5, are employed in the fabrication of organic-inorganic hybrid perovskite solar cells. The corresponding mesoscopic TiO2/CH3NH3PbI3/HTM devices are investigated and compared with that made with commercial spiro-OMeTAD. The best conversion efficiency of 16.56% is achieved for CW4 in the presence of tBp and Li-TFSI as additives and without a cobalt dopant. The performances of CW4 are further examined in terms of conductivity, mobility, morphology, and stability to show its potential as an alternative HTM.

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عنوان ژورنال:
  • Chemical communications

دوره 51 85  شماره 

صفحات  -

تاریخ انتشار 2015